Xeon E5345 's Advantages
Higher base frequency (2.333GHz vs 2.3GHz)
Lower TDP (80W vs 140W)
Intel Xeon W 2191B 's Advantages
Released 11 years and 1 months late
Higher specification of memory (DDR4-2666 vs DDR3
Depends on motherboard)
More modern manufacturing process (14nm vs 65nm)